河北大學化學與環境科學學院研究生導師：武奎

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河北大學化學與環境科學學院研究生導師武奎介紹如下：

1、個人簡介

武奎，男，2013年6月在山東大學晶體材料國家重點實驗室獲得工學博士學位(碩博連讀);2013.7-2018.8在中科院新疆理化所工作，任副研究員;2018.9進入河北大學工作，任特聘研究員。近十年間一直從事光電功能晶體材料的研發工作，到目前為止在材料、光學以及化學等雜志上以第一和通訊作者發表文章32

篇，其中第一 18 篇，通訊 14篇)，其中包括國際知名雜志Coord. Chem. Rev.(1篇)，J. Am. Chem. Soc.(2篇)，Angew. Chem. Int. Ed.(1篇)，chemical sciences (1篇)，Chem. Mater.(1篇)，Chem. Commun.(2篇)。申請中國發明專利14項(授權 6 項)。研究成果獲2015年新疆第十屆青年學術年會優秀論文一等

獎，2016年自治區自然科學優秀學術論文二等獎，并在《Science Foundation in China》期刊上宣傳報道。入選2017年“萬人計劃”后備人選-青年拔尖人才(全疆3人)、自治區青年科技創新人才培養工程，主持國家自然科學基金面上和青年基金、中科院裝備研制項目、中科院西部之光、自治區自然科學基金、重

點實驗室開放課題等。獲得榮譽有2014年新疆自治區科技進步一等獎、2015年烏魯木齊市科技進步一等獎，2012年研究生國家獎學金、新疆創新創業大賽獎。

郵箱：wukui@ms.xjb.ac.cn

熱烈歡迎各位學生報考研究生，歡迎到化學樓207(辦公室)和逸夫樓實驗室參觀交流!

2、主要研究方向

1)硫屬半導體材料的設計與合成;

2)紅外非線性光學晶體材料的研發;

3)稀土熒光材料的合成及性能表征;

4)大尺寸單晶體的生長(提拉、光浮區、坩堝下降法等)及激光性能測試

3、教育和工作經歷

2008/09-2013/06 山東大學晶體材料國家重點實驗室，材料學，碩博連讀 導師：張懷金教授(杰青)

2013/07-2016/09 中國科學院新疆理化技術研究所，助理研究員

2016/09-2018.8 中國科學院新疆理化技術研究所，副研究員

2018.9- 河北大學，特聘研究員

4、第一及通訊作者文章

1. Kui Wu, Yu Chu, Zhihua Yang, Shilie Pan,* Concurrently wide bandgaps and good nonlinear optical responses in A2SrMIVS4 (A = Li, Na; MIV = Ge, Sn) as new potential infrared nonlinear optical materials. Chem. Sci., 2019, 10,3963. (IF= 9.063)

2. Kui Wu, Shilie Pan,* A review on structure−performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances. Coord. Chem. Rev. 2018, 377, 191-208(IF = 14.499)

3. Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan,* New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials. J. Am. Chem. Soc. 2017, 139, 14885−14888. (IF = 14.357)

4. Guangmao Li, Kui Wu,* Qiong Liu, Zhihua Yang, Shilie Pan,* Na2ZnGe2S6: A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold. J. Am. Chem. Soc. 2016, 138, 7422−7428. (IF = 14.357)

5. Kui Wu, Zhihua Yang, Shilie Pan,* Na2BaMQ4 (M = Ge, Sn; Q = S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations. Angew. Chem. Int. Ed. 2016, 55, 6713–6715. (一區，IF = 12.102)

6. Kui Wu, Zhihua Yang, Shilie Pan,* Na2Hg3M2S8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds. Chem. Mater. 2016, 28, 2795−2801. (IF = 9.890)

7. Kui Wu, Zhihua Yang, Shilie Pan,* A First Quaternary Diamond-like Semiconductor with 10−membered LiS4 Rings Exhibiting Excellent Nonlinear Optical Performances. Chem. Commun. 2017, 53, 3010−3013. (IF = 6.290)

8. Kui Wu, Bingbing Zhang, Zhihua Yang* and Shilie Pan*, Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures. Chem. Commun. 2018, 54, 8269−8272. (IF = 6.290)

9. Kui Wu, Zhihua Yang and Shilie Pan, Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6− Units Exhibiting Large Laser-Damage Thresholds, Inorg. Chem. 2015, 54, 10108. (IF = 4.820)

10. Kui Wu, Xin Su, Shilie Pan, and Zhihua Yang, Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7, Inorg. Chem. 2015, 54, 2772. (IF = 4.820)

11. Yu Chu, Kui Wu,* Xin Su, Zhihua Yang, Shilie Pan*, “Intriguing structural transition inducing variable birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)”. Inorg. Chem. 2018, 57, 11310–11313. (IF = 4.820)

12. Kui Wu, Xin Su, Zhihua Yang, Shilie Pan,* An investigation on new infrared nonlinear optical material: BaCdSnSe4, and three new related centrosymmetric compounds: Ba2SnSe4, Mg2GeSe4, and Ba2Ge2S6, Dalton Trans. 2015, 44, 19856. (IF = 4.177)

13. Kui Wu, Zhihua Yang, Shilie Pan*, Na6Si3S8O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si3S8O]6− units without S–O bonds, Dalton Trans. 2017, 46, 13356. (IF = 4.177)

14. Kui Wu, Liangzhen Hao, Haohai Yu, Zhengping Wang, Jiyang Wang, Huaijin Zhang,* Thermal and laser properties of Nd:Lu3Sc1.5Ga3.5O12 for high power dual-wavelength laser, Opt. Express 2012, 20, 6944. (IF = 3.207)

15. Guangmao Li, Qiong Liu, Kui Wu,* Zhihua Yang and Shilie Pan, Na2CdGe2Q6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses, Dalton Trans. 2017, 46, 2778. (IF = 4.177)

16. Ailijiang Abudurusuli, Kui Wu,* Yilimiranmu Rouzhahong, Zhihua Yang, and Shilie Pan, NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q6)6− dimers. Dalton Trans., 2018, 47, 16044. (IF = 4.177)

17. Leyan Nian, Kui Wu,* Guijie He, Zhihua Yang, Shilie Pan*, Effect of Element-Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu and Ag; MIV = Si, Ge and Sn; Q = S and Se). Inorg. Chem. 2018, 57, 3434–3442. (IF = 4.820)

18. Ni Zhen, Kui Wu,* Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, Huaidong Jiang, Yongjun Dong, Shilie Pan*, BaCdSnS4 and Ba3CdSn2S8: syntheses, structures, and non-linear optical and photoluminescence properties, Dalton Trans. 2016, 45, 10681. (IF = 4.177)

19. Ailijiang Abudurusuli, Kui Wu,* Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan,* Na6Zn3MIII2Q9 (MIII = Ga, In; Q = S, Se): four new supertetrahedron layered chalcogenides with unprecedented vertex-sharing T3-clusters and desirable photoluminescence performances, Inorg. Chem. Front. 2018,

5, 1415. (IF = 4.036)

20. Kui Wu, Shilie Pan*, Zhihua Yang, Ba2GeS4 and Mg2SnS4: synthesis, structures, optical properties and electronic structures, RSC Adv. 2015, 5, 33646. (IF = 3.289)

21. Ailijiang Abudurusuli, Kui Wu,* Shilie Pan*, Four New Quaternary Chalcogenides A2Ba7Sn4Q16 (A=Li, Na; Q=S, Se): Syntheses, Crystal structures, Nonlinear Optical Performances, New J. Chem. 2018, 42, 3350. (IF = 3.269)

22. Leyan Nian, Junben Huang, Kui Wu*, Zhi Su, Zhihua Yang, Shilie Pan*, BaCu2MIVQ4 (MIV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations, RSC Adv. 2017, 7, 29378. (IF = 3.289)

23. Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu *, Shilie Pan*, A high laser damage threshold and a good second-harmonic generation response in a new infrared NLO material: LiSm3SiS7, Crystals 2016, 6, 121. (IF = 2.075)

24. Ailijiang Abudurusulia, Hanqin Ding, Kui Wu*, Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13, J. Solid State Chem. 2017, 255, 133. (IF = 2.316)

25. Yu Chu, Guangmao Li, Xin Su, Kui Wu, Shilie Pan, A review on the development of infrared nonlinear optical materials with triangular anionic groups, J. Solid State Chem. 271 (2019) 266–272

26. Xiaowen Wu, Xiaofeng Gu, Hui Pan, Yi Hu, and Kui Wu*, Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe5, Crystals 2018, 8, 165. (IF = 2.074)

27. Kui Wu, Shilie Pan*, Li2HgMS4 (M = Si, Ge, Sn): new quaternary diamond-like semiconductors for infrared laser frequency conversion, Crystals 2017, 7, 107. (IF = 2.074)

28. Kui Wu, Liangzhen Hao, Huaijin Zhang,* Haohai Yu, Yicheng Wang, Jiyang Wang, Xueping Tian, Zhichao Zhou, Junhai Liu, Robert I. Boughton, Lu3Ga5O12 crystal: exploration of new laser host material for the ytterbium ion, J. Opt. Soc. Am. B 2012, 29, 2320. (IF = 1.731)

29. Kui Wu, Liangzhen Hao, Huaijin Zhang,* Haohai Yu, Hengjiang Cong, Jiyang Wang, Growth and characterization of Nd:Lu3ScxGa5−xO12 series laser crystals, Opt. Commun. 2011, 284, 5192. (IF = 1.480)

30. Kui Wu, Bin Yao, Huaijin Zhang,* Haohai Yu, Zhengping Wang, Jiyang Wang, Minhua Jiang, Growth and properties of Nd:Lu3Ga5O12 laser crystal by floating-zone method, J. Cryst. Growth 2010, 312, 3631. (IF = 1.462)

31. Guangmao Li, Kui Wu,* Qiong Liu, Zhihua Yang, Shilie Pan*, Na2ZnSn2S6: A Mixed-metal Thiostannate with Large Second-harmonic Generation Response Activated by Penta-tetrahedral [ZnSn4S14]10- Clusters, Sci. China Technol. Sci. 2017, 60, 1465. (IF = 1.719)

32. Kui Wu, Shilie Pan*, Hongping Wu, Zhihua Yang, Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals, J. Mol. Struct. 2015, 1082, 174. (IF = 1.78)

5、承擔科研項目

主持科研項目共11項。

1)國家自然科學基金面上項目，2019/1-2022/12，60萬元

2)國家自然科學基金青年項目，2015/01-2017/12，25萬元，已結題

3)中科院科研裝備研制項目，2018/1-2019/12，295萬元

4)“萬人計劃”后備-青年拔尖人才(全疆3人)，2017/6-2018/6，10萬元

5)中科院西部之光“西部博士”項目，2013/09-2017/08，40萬元

6)新疆自治區重點實驗室開放課題，2017/1-2019/12，20萬元

7)新疆自治區自然科學基金面上項目，2018/7-2021/6，7萬元

8)新疆自治區青年科技創新人才培養工程，2014/10-2016/09，5萬元

9)新疆自治區自然科學基金青年項目，2014/01-2016/12，5萬元

10)中科院重點實驗室開放課題，2016/1-2018/12，2萬元

11)企業委托項目，2015/01-2016/12，25萬元

6、授權專利

目前已申請中國發明專利14項，授權6項。

(1) 張懷金，武奎，于浩海，王繼揚，一種石榴石結構復合激光晶體的制備方法，2015.4.22， 201210016934.5

(2) 張懷金，武奎，于浩海，王繼揚，一種多段摻雜濃度梯度的石榴石復合晶體及其生長方法，2014.11.5，201210016919.0

(3) 張懷金，武奎，于浩海，王繼揚，激光激活離子摻雜濃度梯度的釩酸鹽復合晶體及其制備方法，2014.10.22，201210016920.3

(4) 張懷金，武奎，于浩海，王繼揚，一種具有鋯英石結構釩酸鹽復合激光晶體的制備方法，2014.9.10，201210016946.8

(5) 于浩海，武奎，郝良振，王正平，張懷金，王繼揚，Nd:YGG晶體1111 nm激光器及在一氧化碳中毒檢測中的應用，2012.7.11，201110006592.4

(6) 張懷金，武奎，郝良振，于浩海，王繼揚，高溫稀土氧化物激光晶體及其制備方法，2012.2.15，201010190075.2

7、獲獎情況

2014年 新疆自治區科技進步一等獎(排名12)

2015年 烏魯木齊市科技進步一等獎(排名5)

2015年 新疆第十屆青年學術年會優秀論文一等獎

2016年 2016年自治區自然科學優秀學術論文二等獎

2015年 新疆創新創業大賽第4名(三等獎)

2012年 博士研究生國家獎學金